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A<sc>bstract</sc> In studying secondary gamma-ray emissions from Primordial Black Holes (PBHs), the production of scalar particles like pions and axion-like particles (ALPs) via Hawking radiation is crucial. While previous analyses assumed relativistic production, asteroid-mass PBHs, relevant to upcoming experiments like AMEGO-X, likely produce pions and ALPs non-relativistically when their masses exceed 10 MeV. To account for mass dependence in Hawking radiation, we revisit the greybody factors for massive scalars from Schwarzschild black holes, revealing significant mass corrections to particle production rates compared to the projected AMEGO-X sensitivity. We highlight the importance of considering non-relativisticπ⁰production in interpreting PBH gamma-ray signals, essential for determining PBH properties. Additionally, we comment on the potential suppression of pion production due to form factor effects when producing extended objects via Hawking radiation. We also provide an example code for calculating the Hawking radiation spectrum of massive scalar particles Image missing<#comment/>.